9,10-Dithioanthracene

Summary

9,10-Dithioanthracene (DTA) is an organic molecule and a derivative of anthracene with two thiol groups. In 2004, DTA molecules were demonstrated to be able to "walk" in a straight line (reportedly a first[citation needed]) on a metal surface by, in effect, mimicking the bipedal motion of a human being.[1][2] The sulfur-bearing functional groups on either side (referred to as "linkers") serve as the molecule's "feet". When the compound is heated on a flat copper surface, the linkers raise up, alternating from side to side, and propel the molecule forward.

9,10-Dithioanthracene
Skeletal formula
Ball-and-stick model
Names
Preferred IUPAC name
Anthracene-9,10-dithiol
Identifiers
  • 86756-29-8 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 742334
  • 849498
UNII
  • 33VPM79CLP checkY
  • DTXSID10357294 Edit this at Wikidata
  • InChI=1S/C14H10S2/c15-13-9-5-1-2-6-10(9)14(16)12-8-4-3-7-11(12)13/h1-8,15-16H ☒N
    Key: QHWTVIYSEHVEKU-UHFFFAOYSA-N ☒N
  • SC1=C2C(C=CC=C2)=C(S)C3=CC=CC=C31
Properties
C14H10S2
Molar mass 242.35 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

During testing at UC Riverside's Center for Nanoscale Science and Engineering, the molecule took about 10,000 unassisted nano-scale steps, moving in a straight line without requiring the assistance of nano-rails or nano-grooves for guidance. As described by one of the researchers, "Similar to a human walking, where one foot is kept on the ground while the other moves forward and propels the body, our molecule always has one linker on a flat surface, which prevents the molecule from stumbling to the side or veering off course."[3][4] Researchers believe the project could lead to the development of molecular computers in which DTA or other similar molecules would function as nano-abacuses.

References edit

  1. ^ Molecular Machines and Motors Recent Advances and Perspectives Series: Topics in Current Chemistry, Vol. 354 Credi, Alberto, Silvi, Serena, Venturi, Margherita (Eds.) 2014
  2. ^ Wilson, Elizabeth K. (September 27, 2005). "Molecules Take A Walk - Unidirectional motion gives researchers control important for molecular machines, self-assembly". C&EN. 83 (40). Retrieved November 5, 2014.
  3. ^ Kwon, KY; Wong, KL; Pawin, G; Bartels, L; Stolbov, S; Rahman, TS (2005). "Unidirectional adsorbate motion on a high-symmetry surface: "walking" molecules can stay the course". Physical Review Letters. 95 (16): 166101. Bibcode:2005PhRvL..95p6101K. doi:10.1103/PhysRevLett.95.166101. PMID 16241817.
  4. ^ "Molecule Walks Like a Human" Archived 2007-08-08 at the Wayback Machine, UC Riverside News Release, September 26, 2005