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Aluminium formate

Summary

Aluminium formate is the aluminium salt of formic acid, with the chemical formula Al(HCOO)3. It can be produced via the reaction of aluminium soaps and formic acid.[1] Reaction between formic acid and aluminium hydroxide yields Al(HCOO)3(CO2)0.75(H2O)0.25(HCOOH)0.25. Upon activation at 180 °C, guest molecules are removed to obtain Al(HCOO)3.[2]

Aluminium formate
Names
IUPAC name
Aluminium triformate
Identifiers
  • 7360-53-4 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 56385
ECHA InfoCard 100.028.089 Edit this at Wikidata
  • 62632
UNII
  • 0D34IG724V checkY
  • DTXSID1044724 Edit this at Wikidata
  • InChI=1S/3CH2O2.Al/c3*2-1-3;/h3*1H,(H,2,3);/q;;;+3/p-3
    Key: MJWPFSQVORELDX-UHFFFAOYSA-K
  • InChI=1/3CH2O2.Al/c3*2-1-3;/h3*1H,(H,2,3);/q;;;+3/p-3
    Key: MJWPFSQVORELDX-DFZHHIFOAF
  • [Al+3].[O-]C=O.[O-]C=O.[O-]C=O
Properties
C3H3AlO6
Molar mass 162.033 g·mol−1
Appearance White powder
Insoluble
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

References edit

  1. ^ Oskar, Jochem. "ALUMINIUM FORMATE AND PROCESS OF MAKING THE SAME". United States Patent Office. Retrieved 2012-06-29.
  2. ^ Evans H A, Mullangi D, Deng Z, et al. Aluminium formate, Al(HCOO)3: An earth-abundant, scalable, and highly selective material for CO2 capture. Science Advances, 2022, 8(44): eade1473. doi:10.1126/sciadv.ade1473

Further reading edit

  • Hannelore, Rauh; Wilhelm Knoche (2010-06-10). "A kinetic study of the formation of aluminium formate in aqueous solution". Berichte der Bunsengesellschaft für physikalische Chemie. 83 (5): 518–521. doi:10.1002/bbpc.19790830513.
  • Xue, Moxi; Gao, Baoyu; Li, Ruihua; Sun, Jianzhang (2018). "Aluminium formate (AF): Synthesis, characterization and application in dye wastewater treatment". Journal of Environmental Sciences. 74: 95–106. doi:10.1016/j.jes.2018.02.013. PMID 30340679. S2CID 53010618.