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Deuterated dichloromethane

Summary

Deuterated dichloromethane (CD2Cl2) is a form (isotopologue) of dichloromethane (DCM, CH2Cl2) in which the hydrogen atoms (H) are deuterium (heavy hydrogen) (2H or D).[1] Deuterated DCM is not a common solvent used in NMR spectroscopy as it is expensive compared to deuterated chloroform.

Deuterated dichloromethane
Stereo, skeletal formula of deuterated dichloromethane
Stereo, skeletal formula of deuterated dichloromethane
Spacefill model of deuterated dichloromethane
Spacefill model of deuterated dichloromethane
Names
Preferred IUPAC name
Dichloro(2H2)methane
Identifiers
  • 1665-00-5
3D model (JSmol)
  • Interactive image
1733318
ChemSpider
  • 141111 checkY
ECHA InfoCard 100.015.252 Edit this at Wikidata
EC Number
  • 216-776-0
  • 160586
UN number 1593
  • DTXSID80937204 Edit this at Wikidata
  • InChI=1S/CH2Cl2/c2-1-3/h1H2/i1D2 checkY
    Key: YMWUJEATGCHHMB-DICFDUPASA-N checkY
  • [2H]C([2H])(Cl)Cl
Properties
C2H2Cl2 or CD2Cl2
Molar mass 86.945 g mol−1
Density 1.362 g cm−3
Boiling point 40 °C (104 °F; 313 K)
Vapor pressure 52.6 kPa (at 20 °C)
Hazards
GHS labelling:
GHS07: Exclamation markGHS08: Health hazard
Warning
H315, H319, H335, H351, H373
P201, P202, P260, P261, P264, P271, P280, P281, P302+P352, P304+P340, P305+P351+P338, P308+P313, P312, P314, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
2
1
0
Related compounds
Related compounds
 Deuterated chloroform

Dichloromethane

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

References edit

  1. ^ Bertolini, Alessandro; Carelli, Giorgio; Moretti, Augusto; Moruzzi, Giovanni (2001). "Assignment of Fir Laser Lines of Fully Deuterated Dichloromethane". International Journal of Infrared and Millimeter Waves. 22 (10): 1421–1431. doi:10.1023/A:1015082422018. S2CID 116030713.