Endothermic process

Summary

In thermochemistry, an endothermic process is any process with an increase in the enthalpy H (or internal energy U) of the system.[1] In such a process, a closed system usually absorbs thermal energy from its surroundings, which is heat transfer into the system. It may be a chemical process, such as dissolving ammonium nitrate (NH4NO3) in water (H2O), or a physical process, such as the melting of ice cubes.

The term was coined by Marcellin Berthelot from the Greek roots endo-, derived from the word "endon" (ἔνδον) meaning "within", and the root "therm" (θερμ-), meaning "hot" or "warm" in the sense that a process depends on absorbing heat if it is to proceed. The opposite of an endothermic process is an exothermic process, one that releases or "gives out" energy, usually in the form of heat and sometimes as electrical energy.[2] Thus in each term (endothermic and exothermic) the prefix refers to where heat (or electrical energy) goes as the process occurs.

So Endothermic reaction is where heat energy is high inside the substance and reduces the thermal energy outside the substance(outside the substance the temperature drops and the temperature increases inside the substance.)

In chemistryEdit

Due to bonds breaking and forming during various processes (changes in state, chemical reactions), there is usually a change in energy. If the energy of the forming bonds is greater than the energy of the breaking bonds, then energy is released. This is known as an exothermic reaction. However, if more energy is needed to break the bonds than the energy being released, energy is taken up. Therefore, it is an endothermic reaction.[3]

DetailsEdit

Whether a process can occur spontaneously depends not only on the enthalpy change but also on the entropy change (∆S) and absolute temperature T. If a process is a spontaneous process at a certain temperature, the products have a lower Gibbs free energy G = H - TS than the reactants (an exergonic process),[1] even if the enthalpy of the products is higher. Thus, an endothermic process usually requires a favorable entropy increase (∆S > 0) in the system that overcomes the unfavorable increase in enthalpy so that still ∆G < 0. While endothermic phase transitions into more disordered states of higher entropy, e.g. melting and vaporization, are common, spontaneous chemical processes at moderate temperatures are rarely endothermic. The enthalpy increase ∆H >> 0 in a hypothetical strongly endothermic process usually results in ∆G = ∆H -TS > 0, which means that the process will not occur (unless driven by electrical or photon energy). An example of an endothermic and exergonic process is

C6H12O6 + 6 H2O → 12 H2 + 6 CO2, ∆r = +627 kJ/mol, ∆r = -31 kJ/mol

ExamplesEdit

Distinction between endothermic and endothermEdit

The terms "endothermic" and "endotherm" are both derived from Greek ἔνδον endon "within" and θέρμη thermē "heat", but depending on context, they can have very different meanings.

In physics, thermodynamics applies to processes involving a system and its surroundings, and the term "endothermic" is used to describe a reaction where energy is taken "(with)in" by the system (vs. an "exothermic" reaction, which releases energy "outwards").

In biology, thermoregulation is the ability of an organism to maintain its body temperature, and the term "endotherm" refers to an organism that can do so from "within" by using the heat released by its internal bodily functions (vs. an "ectotherm", which relies on external, environmental heat sources) to maintain an adequate temperature.

ReferencesEdit

  1. ^ a b Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).Principle of Modern Chemistry, Brooks Cole. p. 617. ISBN 978-1305079113
  2. ^ Schmidt-Rohr, K. (2018). "How Batteries Store and Release Energy: Explaining Basic Electrochemistry" ‘’J. Chem. Educ.’’ 95: 1801-1810. http://dx.doi.org/10.1021/acs.jchemed.8b00479
  3. ^ "Exothermic & Endothermic Reactions | Energy Foundations for High School Chemistry". highschoolenergy.acs.org. Retrieved 2021-04-11.
  4. ^ Austin, Patrick (January 1996). "Tritium: The environmental, health, budgetary, and strategic effects of the Department of Energy's decision to produce tritium". Institute for Energy and Environmental Research. Retrieved 2010-09-15.
  5. ^ Qian, Y.-Z.; Vogel, P.; Wasserburg, G. J. (1998). "Diverse Supernova Sources for the r-Process". Astrophysical Journal 494 (1): 285–296. arXiv:astro-ph/9706120. Bibcode:1998ApJ...494..285Q. doi:10.1086/305198.
  6. ^ "Messing with Mass". WGBH. 2005. Retrieved 2020-05-28.

External linksEdit

  • Endothermic Definition – MSDS Hyper-Glossary