We are looking for solutions ${\displaystyle \psi (k,r)}$  to the radial Schrödinger equation in the case ${\displaystyle \ell =0}$ ,

${\displaystyle -\psi ''+V\psi =k^{2}\psi .}$ 

A regular solution ${\displaystyle \varphi (k,r)}$  is one that satisfies the boundary conditions,

${\displaystyle {\begin{aligned}\varphi (k,0)&=0\\\varphi _{r}'(k,0)&=1.\end{aligned}}}$ 

If ${\displaystyle \int _{0}^{\infty }r|V(r)|<\infty }$ , the solution is given as a Volterra integral equation,

${\displaystyle \varphi (k,r)=k^{-1}\sin(kr)+k^{-1}\int _{0}^{r}dr'\sin(k(r-r'))V(r')\varphi (k,r').}$ 

There are two irregular solutions (sometimes called Jost solutions) ${\displaystyle f_{\pm }}$  with asymptotic behavior ${\displaystyle f_{\pm }=e^{\pm ikr}+o(1)}$  as ${\displaystyle r\to \infty }$ . They are given by the Volterra integral equation,

${\displaystyle f_{\pm }(k,r)=e^{\pm ikr}-k^{-1}\int _{r}^{\infty }dr'\sin(k(r-r'))V(r')f_{\pm }(k,r').}$ 

If ${\displaystyle k\neq 0}$ , then ${\displaystyle f_{+},f_{-}}$  are linearly independent. Since they are solutions to a second order differential equation, every solution (in particular ${\displaystyle \varphi }$ ) can be written as a linear combination of them.

The Jost function is

${\displaystyle \omega (k):=W(f_{+},\varphi )\equiv \varphi _{r}'(k,r)f_{+}(k,r)-\varphi (k,r)f_{+,r}'(k,r)}$ ,

where W is the Wronskian. Since ${\displaystyle f_{+},\varphi }$  are both solutions to the same differential equation, the Wronskian is independent of r. So evaluating at ${\displaystyle r=0}$  and using the boundary conditions on ${\displaystyle \varphi }$  yields ${\displaystyle \omega (k)=f_{+}(k,0)}$ .

The Jost function can be used to construct Green's functions for

${\displaystyle \left[-{\frac {\partial ^{2}}{\partial r^{2}}}+V(r)-k^{2}\right]G=-\delta (r-r').}$ 

In fact,

${\displaystyle G^{+}(k;r,r')=-{\frac {\varphi (k,r\wedge r')f_{+}(k,r\vee r')}{\omega (k)}},}$ 

where ${\displaystyle r\wedge r'\equiv \min(r,r')}$  and ${\displaystyle r\vee r'\equiv \max(r,r')}$ .

• Newton, Roger G. (1966). Scattering Theory of Waves and Particles. New York: McGraw-Hill. OCLC 362294.
• Yafaev, D. R. (1992). Mathematical Scattering Theory. Providence: American Mathematical Society. ISBN 0-8218-4558-6.