Lithium_methoxide Knowpia

Lithium methoxide
Names
	IUPAC name Lithium methoxide
	Other names Lithium methanolate
Identifiers
CAS Number	865-34-9;
3D model (JSmol)	Interactive image;
ChemSpider	144418;
ECHA InfoCard	100.011.580
PubChem CID	164741;
CompTox Dashboard (EPA)	DTXSID00890529 ;
	InChI InChI=1S/CH3O.Li/c1-2;/h1H3;/q-1;+1 Key: JILPJDVXYVTZDQ-UHFFFAOYSA-N; InChI=1/CH3O.Li/c1-2;/h1H3;/q-1;+1 Key: JILPJDVXYVTZDQ-UHFFFAOYAW;
	SMILES [Li+].[O-]C;
Properties
Chemical formula	CH3LiO
Molar mass	37.975
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Lithium methoxide is a compound with formula LiCH₃O. It is the lithium salt of methanol. Like other alkali metal alkoxides, lithium methoxide adopts a polymeric structure^[1] Its solubility in common polar aprotic solvents like THF is low; however, it is soluble in methanol and is available commercially as a 10% solution.^[2]

References edit

^ WHEATLEY, P. J. (1960-03-05). "Structure of Lithium Methoxide". Nature. 185 (4714): 681–682. Bibcode:1960Natur.185..681W. doi:10.1038/185681b0. S2CID 6915735.
^ "Lithium Methoxide (LiOMe) in 10% Methanol" (PDF). FMC lithium. 2016. Archived from the original (PDF) on 6 September 2017. Retrieved 6 Sep 2017.

[1] WHEATLEY, P. J. (1960-03-05). "Structure of Lithium Methoxide". Nature. 185 (4714): 681–682. Bibcode:1960Natur.185..681W. doi:10.1038/185681b0. S2CID 6915735.

[2] "Lithium Methoxide (LiOMe) in 10% Methanol" (PDF). FMC lithium. 2016. Archived from the original (PDF) on 6 September 2017. Retrieved 6 Sep 2017.

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[2]

Summary

See also edit

References edit