Manganese pentacarbonyl bromide is an organomanganese compound with the formula BrMn(CO)5. It is a bright orange solid that is a precursor to other manganese complexes. The compound is prepared by treatment of dimanganese decacarbonyl with bromine:[1]
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Other names
bromopentacarbonylmanganese
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Identifiers | |
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3D model (JSmol)
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ChemSpider |
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ECHA InfoCard | 100.035.005 |
EC Number |
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PubChem CID
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Properties | |
C5BrMnO5 | |
Molar mass | 274.892 g·mol−1 |
Appearance | orange solid |
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H302, H312, H332 | |
P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P312, P322, P330, P363, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
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The complex undergoes substitution by a variety of donor ligands (L), e.g. to give derivatives of the type BrMn(CO)3L2.
The complex adopts an octahedral coordination geometry.[2]