In particular, a family of lattice planes of a given (direct) Bravais lattice is determined by three integers h, k, and ℓ, the Miller indices. They are written (hkℓ), and denote the family of (parallel) lattice planes (of the given Bravais lattice) orthogonal to , where are the basis or primitive translation vectors of the reciprocal lattice for the given Bravais lattice. (Note that the plane is not always orthogonal to the linear combination of direct or original lattice vectors because the direct lattice vectors need not be mutually orthogonal.) This is based on the fact that a reciprocal lattice vector (the vector indicating a reciprocal lattice point from the reciprocal lattice origin) is the wavevector of a plane wave in the Fourier series of a spatial function (e.g., electronic density function) which periodicity follows the original Bravais lattice, so wavefronts of the plane wave are coincident with parallel lattice planes of the original lattice. Since a measured scattering vector in X-ray crystallography, with as the outgoing (scattered from a crystal lattice) X-ray wavevector and as the incoming (toward the crystal lattice) X-ray wavevector, is equal to a reciprocal lattice vector as stated by the Laue equations, the measured scattered X-ray peak at each measured scattering vector is marked by Miller indices. By convention, negative integers are written with a bar, as in 3 for −3. The integers are usually written in lowest terms, i.e. their greatest common divisor should be 1. Miller indices are also used to designate reflections in X-ray crystallography. In this case the integers are not necessarily in lowest terms, and can be thought of as corresponding to planes spaced such that the reflections from adjacent planes would have a phase difference of exactly one wavelength (2π), regardless of whether there are atoms on all these planes or not.
There are also several related notations:
In the context of crystal directions (not planes), the corresponding notations are:
Miller indices were introduced in 1839 by the British mineralogist William Hallowes Miller, although an almost identical system (Weiss parameters) had already been used by German mineralogist Christian Samuel Weiss since 1817. The method was also historically known as the Millerian system, and the indices as Millerian, although this is now rare.
The Miller indices are defined with respect to any choice of unit cell and not only with respect to primitive basis vectors, as is sometimes stated.
There are two equivalent ways to define the meaning of the Miller indices: via a point in the reciprocal lattice, or as the inverse intercepts along the lattice vectors. Both definitions are given below. In either case, one needs to choose the three lattice vectors a1, a2, and a3 that define the unit cell (note that the conventional unit cell may be larger than the primitive cell of the Bravais lattice, as the examples below illustrate). Given these, the three primitive reciprocal lattice vectors are also determined (denoted b1, b2, and b3).
Then, given the three Miller indices h, k, ℓ, (hkℓ) denotes planes orthogonal to the reciprocal lattice vector:
That is, (hkℓ) simply indicates a normal to the planes in the basis of the primitive reciprocal lattice vectors. Because the coordinates are integers, this normal is itself always a reciprocal lattice vector. The requirement of lowest terms means that it is the shortest reciprocal lattice vector in the given direction.
Equivalently, (hkℓ) denotes a plane that intercepts the three points a1/h, a2/k, and a3/ℓ, or some multiple thereof. That is, the Miller indices are proportional to the inverses of the intercepts of the plane, in the basis of the lattice vectors. If one of the indices is zero, it means that the planes do not intersect that axis (the intercept is "at infinity").
Considering only (hkℓ) planes intersecting one or more lattice points (the lattice planes), the perpendicular distance d between adjacent lattice planes is related to the (shortest) reciprocal lattice vector orthogonal to the planes by the formula: .
The related notation [hkℓ] denotes the direction:
That is, it uses the direct lattice basis instead of the reciprocal lattice. Note that [hkℓ] is not generally normal to the (hkℓ) planes, except in a cubic lattice as described below.
For the special case of simple cubic crystals, the lattice vectors are orthogonal and of equal length (usually denoted a), as are those of the reciprocal lattice. Thus, in this common case, the Miller indices (hkℓ) and [hkℓ] both simply denote normals/directions in Cartesian coordinates.
For cubic crystals with lattice constant a, the spacing d between adjacent (hkℓ) lattice planes is (from above)
Because of the symmetry of cubic crystals, it is possible to change the place and sign of the integers and have equivalent directions and planes:
For face-centered cubic and body-centered cubic lattices, the primitive lattice vectors are not orthogonal. However, in these cases the Miller indices are conventionally defined relative to the lattice vectors of the cubic supercell and hence are again simply the Cartesian directions.
Here h, k and ℓ are identical to the corresponding Miller indices, and i is a redundant index.
This four-index scheme for labeling planes in a hexagonal lattice makes permutation symmetries apparent. For example, the similarity between (110) ≡ (1120) and (120) ≡ (1210) is more obvious when the redundant index is shown.
In the figure at right, the (001) plane has a 3-fold symmetry: it remains unchanged by a rotation of 1/3 (2π/3 rad, 120°). The ,  and the  directions are really similar. If S is the intercept of the plane with the  axis, then
There are also ad hoc schemes (e.g. in the transmission electron microscopy literature) for indexing hexagonal lattice vectors (rather than reciprocal lattice vectors or planes) with four indices. However they don't operate by similarly adding a redundant index to the regular three-index set.
For example, the reciprocal lattice vector (hkℓ) as suggested above can be written in terms of reciprocal lattice vectors as . For hexagonal crystals this may be expressed in terms of direct-lattice basis-vectors a1, a2 and a3 as
Hence zone indices of the direction perpendicular to plane (hkℓ) are, in suitably normalized triplet form, simply . When four indices are used for the zone normal to plane (hkℓ), however, the literature often uses instead. Thus as you can see, four-index zone indices in square or angle brackets sometimes mix a single direct-lattice index on the right with reciprocal-lattice indices (normally in round or curly brackets) on the left.
And, note that for hexagonal interplanar distances, they take the form
Crystallographic directions are lines linking nodes (atoms, ions or molecules) of a crystal. Similarly, crystallographic planes are planes linking nodes. Some directions and planes have a higher density of nodes; these dense planes have an influence on the behavior of the crystal:
For all these reasons, it is important to determine the planes and thus to have a notation system.
Ordinarily, Miller indices are always integers by definition, and this constraint is physically significant. To understand this, suppose that we allow a plane (abc) where the Miller "indices" a, b and c (defined as above) are not necessarily integers.
If a, b and c have rational ratios, then the same family of planes can be written in terms of integer indices (hkℓ) by scaling a, b and c appropriately: divide by the largest of the three numbers, and then multiply by the least common denominator. Thus, integer Miller indices implicitly include indices with all rational ratios. The reason why planes where the components (in the reciprocal-lattice basis) have rational ratios are of special interest is that these are the lattice planes: they are the only planes whose intersections with the crystal are 2d-periodic.
For a plane (abc) where a, b and c have irrational ratios, on the other hand, the intersection of the plane with the crystal is not periodic. It forms an aperiodic pattern known as a quasicrystal. This construction corresponds precisely to the standard "cut-and-project" method of defining a quasicrystal, using a plane with irrational-ratio Miller indices. (Although many quasicrystals, such as the Penrose tiling, are formed by "cuts" of periodic lattices in more than three dimensions, involving the intersection of more than one such hyperplane.)
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