|Systematic IUPAC name
3D model (JSmol)
CompTox Dashboard (EPA)
|Molar mass||264.01 g·mol−1|
|Appearance||Vivid, white, translucent crystals|
|Density||1.96 g cm−3|
|Melting point||150 °C (302 °F; 423 K)|
|Boiling point||156 °C (313 °F; 429 K)|
|Solubility||soluble in benzene, paraffin oil |
slightly soluble in ether
Std enthalpy of
|−989.1 kJ mol−1|
Std enthalpy of
|−2123.4 kJ mol−1|
|H300, H310, H315, H319, H330, H413|
|P261, P271, P280, P304+P340+P311, P405, P501|
|NFPA 704 (fire diamond)|
|Safety data sheet (SDS)||External MSDS|
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
|(what is ?)|
Molybdenum hexacarbonyl (also called molybdenum carbonyl) is the chemical compound with the formula Mo(CO)6. This colorless solid, like its chromium and tungsten analogues, is noteworthy as a volatile, air-stable derivative of a metal in its zero oxidation state.
Mo(CO)6 adopts an octahedral geometry consisting of six rod-like CO ligands radiating from the central Mo atom. A recurring minor debate in some chemical circles concerns the definition of an "organometallic" compound. Usually, organometallic indicates the presence of a metal directly bonded via a M–C bond to an organic fragment, which must in turn have a C–H bond.
Mo(CO)6 is prepared by the reduction of molybdenum chlorides or oxides under a pressure of carbon monoxide, although it would be unusual to prepare this inexpensive compound in the laboratory. The compound is somewhat air-stable and sparingly soluble in nonpolar organic solvents.
Molybdenum hexacarbonyl is a popular reagent in academic research.
One or more CO ligands can be displaced by other ligands. Mo(CO)6, [Mo(CO)3(MeCN)3], and related derivatives are employed as catalysts in organic synthesis for example, alkyne metathesis and the Pauson–Khand reaction.
The thermal reaction of Mo(CO)6 with piperidine affords Mo(CO)4(piperidine)2. The two piperidine ligands in this yellow-colored compound are labile, which allows other ligands to be introduced under mild conditions. For instance, the reaction of [Mo(CO)4(piperidine)2] with triphenyl phosphine in boiling dichloromethane (b.p. ca. 40 °C) gives cis-[Mo(CO)4(PPh3)2]. This cis- complex isomerizes in toluene to trans-[Mo(CO)4(PPh3)2].
Mo(CO)6 also can be converted to its tris(acetonitrile) derivative. The compound serves as a source of "Mo(CO)3". For instance treatment with allyl chloride gives [MoCl(allyl)(CO)2(MeCN)2], whereas treatment with KTp and sodium cyclopentadienide gives [MoTp(CO)3]− and [MoCp(CO)3]− anions, respectively. These anions react with a variety of electrophiles. A related source of Mo(CO)3 is cycloheptatrienemolybdenum tricarbonyl.
Like all metal carbonyls, Mo(CO)6 is dangerous source of volatile metal as well as CO.