Monoclinic crystal system

Summary

In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic system. They form a rectangular prism with a parallelogram as its base. Hence two pairs of vectors are perpendicular (meet at right angles), while the third pair makes an angle other than 90°.

Monoclinic crystal
An example of the monoclinic crystal orthoclase

Bravais latticesEdit

Two-dimensionalEdit

The only monoclinic Bravais lattice in two dimensions is the oblique lattice.

Bravais lattice Oblique
Pearson symbol mp
Unit cell  

Three-dimensionalEdit

Two monoclinic Bravais lattices exist: the primitive monoclinic and the base-centered monoclinic.

Bravais lattice Primitive
monoclinic
Base-centered
monoclinic
Pearson symbol mP mS
Unit cell    

For the base-centered monoclinic lattice, the primitive cell has the shape of an oblique rhombic prism;[1] it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. Note that the length   of the primitive cell below equals   of the conventional cell above.

Oblique rhombic prism primitive cell
 
Primitive cell of the base-centered monoclinic lattice
 
Relationship between base layers of primitive and conventional cells

Crystal classesEdit

The table below organizes the space groups of the monoclinic crystal system by crystal class. It lists the International Tables for Crystallography space group numbers,[2] followed by the crystal class name, its point group in Schoenflies notation, Hermann–Mauguin (international) notation, orbifold notation, and Coxeter notation, type descriptors, mineral examples, and the notation for the space groups.

# Point group Type Example Space groups
Name[3] Schön. Intl Orb. Cox. Primitive Base-centered
3–5 Sphenoidal C2 2 22 [2]+ enantiomorphic polar halotrichite P2, P21 C2
6–9 Domatic Cs (C1h) m *11 [ ] polar hilgardite Pm, Pc Cm, Cc
10–12 Prismatic C2h 2/m 2* [2,2+] centrosymmetric gypsum P2/m, P21/m C2/m
13–15 P2/c, P21/c C2/c

Sphenoidal is also called monoclinic hemimorphic, domatic is also called monoclinic hemihedral, and prismatic is also called monoclinic normal.

The three monoclinic hemimorphic space groups are as follows:

  • a prism with as cross-section wallpaper group p2
  • ditto with screw axes instead of axes
  • ditto with screw axes as well as axes, parallel, in between; in this case an additional translation vector is one half of a translation vector in the base plane plus one half of a perpendicular vector between the base planes.

The four monoclinic hemihedral space groups include

  • those with pure reflection at the base of the prism and halfway
  • those with glide planes instead of pure reflection planes; the glide is one half of a translation vector in the base plane
  • those with both in between each other; in this case an additional translation vector is this glide plus one half of a perpendicular vector between the base planes.

See alsoEdit

ReferencesEdit

  1. ^ See Hahn (2002), p. 746, row mC, column Primitive, where the cell parameters are given as a1 = a2, α = β
  2. ^ Prince, E., ed. (2006). International Tables for Crystallography. International Union of Crystallography. doi:10.1107/97809553602060000001. ISBN 978-1-4020-4969-9.
  3. ^ "The 32 crystal classes". Retrieved 2018-06-19.

Further readingEdit

  • Hurlbut, Cornelius S.; Klein, Cornels (1985). Manual of Mineralogy (20th ed.). pp. 69–73. ISBN 0-471-80580-7.
  • Hahn, Theo, ed. (2002). International Tables for Crystallography, Volume A: Space Group Symmetry. International Tables for Crystallography. Vol. A (5th ed.). Berlin, New York: Springer-Verlag. doi:10.1107/97809553602060000100. ISBN 978-0-7923-6590-7.