Summary
It is used as a non-corroding[1] or 'stainless'[2] uranium alloy.[3] It has been put forward as a structural material for the casings of the physics package in nuclear weapons, including those of North Korea.[4]
The composition is a ternary alloy,[5][6] of 7.5% niobium, 2.5% zirconium, 90% uranium.[3]
Mulberry was developed in the 1960s at UCRL.[6][7] Binary alloy compositions were first studied to avoid the mechanical problems of pure uranium: corrosion, dimensional instability, inability to improve its mechanical properties by heat treatment.[8] Uranium-molybdenum alloys were found susceptible to stress-corrosion cracking, uranium-niobium alloys to be weak, and uranium-zirconium alloys to be brittle.[8] Ternary alloys were next studied to try to avoid these drawbacks. Uranium-niobium-zirconium was found to be corrosion resistant and to permit age hardening, which could increase its hardness from 110 to 270 ksi.[8][9]
Multiple crystal phases were observed, with a critical temperature of 650°C. Above this the body-centered cubic γ phase was stable. Water quenching to room temperature produces a γs transition phase and with aging this transforms to a tetragonal γo phase. Further aging produces a monoclinic ɑ″ phase that is observed metallographically as a Widmanstätten pattern.[10][11] The crystal structure of the alloy has been studied, particularly the γ phase.[6][7][12][13] Uranium inclusions have been observed within the alloy although, unlike the binary alloys, niobium-rich inclusions were not.[14] Early studies were uncertain as to whether these were inherent behaviours, or artifacts of their processing.
References edit
- ^ Larson, D.T. (1971). "Oxidation of a Ternary Uranium Alloy". Journal of Vacuum Science and Technology. 8 (1): 80. Bibcode:1971JVST....8...80L. doi:10.1116/1.1316361.
- ^ Henry, Charles R. (February 26, 1965). Plutonium and Uranium as Engineering Materials (Report). University of California, Lawrence Radiation Laboratory. pp. 7–8. doi:10.2172/4546042. AEC Contract No. W-7405-eng-48. Archived from the original on July 22, 2022. Retrieved November 18, 2017.
- ^ a b "North Korea bargains with nuclear diplomacy" (PDF). Jane's. p. 10. Archived (PDF) from the original on 2017-10-25. Retrieved 2017-11-18.
- ^ Jane's, North Korea, p. 9.
- ^ Williams, R.O. (June 1979). "Stability of the body-centered cubic gamma phase in the uranium-zirconium-niobium system". J. Nucl. Mater. 82 (1): 184–192. Bibcode:1979JNuM...82..184W. doi:10.1016/0022-3115(79)90052-7.
- ^ a b c Vandervoort, R.R.; Peterson, C.A.W. (1964). Mechanical Properties of Some Uranium Alloys (Report). UCRL. doi:10.2172/4560786. UCRL-7771. Archived from the original on 2017-12-01. Retrieved 2017-11-18.
- ^ a b Vandervoort, R.R.; Peterson, C.A.W. (1964). The Properties of a Metastable Gamma Phase Uranium-base Alloy: U-7.5 Nb 2.5 Zr (Report). UCRL. UCRL-7869. Archived from the original on 2017-12-01. Retrieved 2017-11-18.
- ^ a b c Hoge, K.G; Kuhn, B.A.; Reshenk, V.L. (1973). Flow behavior of mulberry uranium (PDF) (Report). Vol. 4. California Univ., Livermore (USA). Lawrence Livermore Lab. UCRL-51346. Archived (PDF) from the original on 2017-12-01. Retrieved 2017-11-18.
- ^ Erickson, W. C.; Jaynes, G. E.; Sandstrcsn, D. J.; Seegmiller, R.; Taub, J. M. (September 1972). Evaluation of Uranium Alloys (Report). LASL. pp. 8–13. Archived from the original on 2017-12-01. Retrieved 2022-07-22.
- ^ Dean, C.W. (24 October 1969). A Study of the Time-Temperature Transformation Behavior of a Uranium=7.5 weight per cent Niobium-2.5 weight per cent Zirconium Alloy (PDF) (Report). Union Carbide Corporation, Y-12 Plant, Oak Ridge National Laboratory. Oak Ridge Report Y-1694. Archived (PDF) from the original on 24 July 2018. Retrieved 18 November 2017.
- ^ Vandermeer, R.A. (1973). Recent Observations of Phase Transformations in a U-Nb-Zr Alloy (Report). Metals and Ceramics Division, Oak Ridge National Laboratory. Archived from the original on 2022-07-22. Retrieved 2017-11-18.
- ^ Abey, A.E.; Joslyn, E.D. (April 1972). "The elastic constants of uranium-7.5% niobium-2.5% zirconium as a function of pressure". J. Less Common Met. 27 (1): 9–15. doi:10.1016/0022-5088(72)90099-9.
- ^ Lopes, Denise Adorno; Restivo, Thomaz Augusto Guisard; de Lima, Nelson Batista; Padilha, Angelo Fernando (2014). "Gamma-phase homogenization and texture in U–7.5Nb–2.5Zr (Mulberry) alloy". Journal of Nuclear Materials. 449, Issues 1–3, June 2014, Pages 23-30 (1–3): 23–30. Bibcode:2014JNuM..449...23L. doi:10.1016/j.jnucmat.2014.02.030.
- ^ Gareth Thomas; Richard M. Fulrath; Robert M. Fisher, eds. (1972). Electron Microscopy and Structure of Materials. University of California Press. pp. 340–345. ISBN 0520021142. Archived from the original on 2022-07-22. Retrieved 2020-09-30.