Reprocessed uranium


Reprocessed uranium (RepU) is the uranium recovered from nuclear reprocessing, as done commercially in France, the UK and Japan and by nuclear weapons states' military plutonium production programs. This uranium makes up the bulk of the material separated during reprocessing.

Commercial LWR spent nuclear fuel contains on average (excluding cladding) only four percent plutonium, minor actinides and fission products by weight. Despite it often containing more fissile material than natural uranium, reuse of reprocessed uranium has not been common because of low prices in the uranium market of recent decades, and because it contains undesirable isotopes of uranium.

Isotopic composition of reprocessed uranium[1]
Isotope Proportion Characteristics
uranium-238 98.5% Fertile material
uranium-237 0% Around 0.001% at discharge, but half-life only 1 week. Produces soluble, long-lived neptunium-237 which is hard to contain in a geological repository. 237
is the feedstock for the production of 238
which is used in Radioisotope thermoelectric generators
uranium-236 0.4%-0.6% Neither fissile nor fertile. Affects reactivity.
uranium-235 0.5%-1.0% Fissile material
uranium-234 >0.02% Fertile material but can affect reactivity differently[2]
uranium-233 trace Fissile material
uranium-232 trace Fertile material, decay product thallium-208 emits strong gamma radiation making handling difficult

Given sufficiently high uranium prices, it is feasible for reprocessed uranium to be re-enriched and reused. A higher enrichment level is required to compensate for the 236U which is lighter than 238U and therefore concentrates in the enriched product.[3] As enrichment concentrates lighter isotopes on the "enriched" side and heavier isotopes on the "depleted" side, 234
will inevitably be enriched slightly stronger than 235
, which is a negligible effect in a once through fuel cycle due to the low (55 ppm) share of 234
in natural uranium but can become relevant after successive passes through an enrichment-burnup-reprocessing-enrichment cycle, depending on enrichment and burnup characteristics. 234
readily absorbs thermal neutrons and converts to fissile 235
which needs to be taken into account if it reaches significant proportions of the fuel material. Also, if fast breeder reactors ever come into commercial use, reprocessed uranium, like depleted uranium, will be usable in their breeding blankets.

There have been some studies involving the use of reprocessed uranium in CANDU reactors. CANDU is designed to use natural uranium as fuel; the 235U content remaining in spent PWR/BWR fuel is typically greater than that found in natural uranium, which is about 0.72% 235U, allowing the re-enrichment step to be skipped. Fuel cycle tests also have included the DUPIC (Direct Use of spent PWR fuel In CANDU) fuel cycle, where used fuel from a Pressurized Water Reactor (PWR) is packaged into a CANDU fuel bundle with only physical reprocessing (cut into pieces) but no chemical reprocessing.[4]

The direct use of recovered uranium to fuel a CANDU reactor was first demonstrated at Qinshan Nuclear Power Plant in China.[5] The first use of re-enriched uranium in a commercial LWR was in 1994 at the Cruas Nuclear Power Plant in France.[6][7]


  1. ^ "Processing of Used Nuclear Fuel". World Nuclear Association. 2013. Retrieved 2014-02-16.
  2. ^ "Uranium from reprocessing". Archived from the original on 2007-10-19.
  3. ^ "Advanced Fuel Cycle Cost Basis" (PDF). Idaho National Laboratory. Archived from the original (PDF) on 2009-01-24.
  4. ^ "The Evolution of CANDU Fuel Cycles and Their Potential Contribution to World Peace". DUPIC.
  5. ^ Use of CANDU fuel from spent light water reactor fuel at Qinshan nuclear power plant
  6. ^ Framatome to supply EDF with reprocessed uranium fuel
  7. ^ EDF plans to restart use of reprocessed uranium in some of its reactors

Further reading

Advanced Fuel Cycle Cost Basis - Idaho National Laboratory

  • Module K2 Aqueously Reprocessed Uranium Conversion and Disposition
  • Module K3 Pyrochemically/Pyrometallurgically Reprocessed Uranium Conversion and Disposition