Rhodium(II) acetate is the coordination compound with the formula Rh2(AcO)4, where AcO− is the acetate ion (CH
3CO−
2). This dark green powder is slightly soluble in polar solvents, including water. It is used as a catalyst for cyclopropanation of alkenes. It is a widely studied example of a transition metal carboxylate complex.
Names | |
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IUPAC name
Rhodium(II) acetate
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Other names
Dirhodium tetraacetate,
Tetrakis(acetato)dirhodium(II), Rhodium diacetate dimer, Tetrakis(μ-acetato)dirhodium | |
Identifiers | |
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3D model (JSmol)
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ChemSpider |
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ECHA InfoCard | 100.036.425 |
EC Number |
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PubChem CID
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RTECS number |
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UNII |
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Properties | |
C8H12O8Rh2 | |
Molar mass | 441.99 g/mol |
Appearance | Emerald green powder |
Density | 1.126 g/cm3 |
Melting point | >100 °C |
Boiling point | decomposes |
soluble | |
Solubility in other solvents | polar organic solvents |
Structure | |
monoclinic | |
octahedral | |
0 D | |
Hazards | |
GHS labelling:[1] | |
Warning | |
H315, H319 | |
P264, P280, P302+P352, P305+P351+P338, P321, P332+P313, P337+P313, P362 | |
NFPA 704 (fire diamond) | |
Flash point | low flammability |
Safety data sheet (SDS) | Coleparmer MSDS |
Related compounds | |
Related compounds
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Copper(II) acetate Chromium(II) acetate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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Rhodium(II) acetate is usually prepared by the heating of hydrated rhodium(III) chloride in acetic acid (CH3COOH):[2] Rhodium(II) acetate dimer undergoes ligand exchange, the replacement of the acetate group by other carboxylates and related groups.[3]
The structure of rhodium(II) acetate features a pair of rhodium atoms, each with octahedral molecular geometry, defined by four acetate oxygen atoms, water, and a Rh–Rh bond of length 2.39 Å. The water adduct is exchangeable, and a variety of other Lewis bases bind to the axial positions.[4] Copper(II) acetate and chromium(II) acetate adopt similar structures.
The application of dirhodium tetraacetate to organic synthesis was pioneered by Teyssie and co-workers.[5] An extensive range of reactions including insertion into bonds and the cyclopropanation of alkenes[6] and aromatic systems.[7] It selectively binds ribonucleosides (vs. deoxynucleosides) by binding selectively to ribonucleosides at their 2′ and 3′ –OH groups.[8] Rhodium(II) acetate dimer, compared to copper(II) acetate, is more reactive and useful in differentiating ribonucleosides and deoxynucleosides because it is soluble in aqueous solution like water whereas copper(II) acetate only dissolves in non-aqueous solution.
Dirhodium tetraacetate is also used as catalyst for insertion into C–H and X–H bonds (X = N, S, O).
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