Tricarbonate

Summary

In organic chemistry, a tricarbonate is a compound containing the divalent −O−C(=O)−O−C(=O)−O−C(=O)−O− functional group, which consists of three carbonate groups linked in a chain by sharing of oxygen atoms. These compounds can be viewed as derivatives of a hypothetical tricarbonic acid, HO−C(=O)−O−C(=O)−O−C(=O)−OH. An important example is di-tert-butyl tricarbonate (H3C−)3C−C3O7−C(−CH3)3, an intermediate in the synthesis of di-tert-butyl dicarbonate.[1]

Tricarbonate ion
Names
IUPAC name
Tricarbonate
Properties
C3O2−7
Molar mass 148.026 g·mol−1
Structure
Trigonal planar at carbon atoms
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

The term tricarbonate is sometimes used for salts that contain three carbonate dianions in their covalent structure or stoichiometric formula, such as cerium tricarbonate Ce2(CO3)3.

See also edit

References edit

  1. ^ Barry M. Pope, Yutaka Yamamoto, and D. Stanley Tarbell (1977), "Di-tert-Butyl Dicarbonate". Organic Syntheses, Vol. 57, p.45; Coll. Vol. 6 (1988) p.418