A twilight phenomenon is produced when exhaust particles from missile or rocket propellant left in the vapor trail of a launch vehicle condense, freeze, and then expand in the less dense upper atmosphere. The exhaust plume, which is suspended against a dark sky, is then illuminated by reflective high-altitude sunlight through dispersion, which produces a spectacular, colorful effect when seen at ground level.

The phenomenon typically occurs with launches that take place either 30 to 60 minutes before sunrise or after sunset when a booster rocket or missile rises out of the darkness and into a sunlit area, relative to an observer's perspective on the ground. Because rocket trails extend high into the stratosphere and mesosphere, they catch high-altitude sunlight long after the sun has set on the ground. The small particles in the expanding exhaust plume or "cloud" diffract sunlight and produce the rose, blue, green and orange colors—much like a dispersive prism can be used to break light up into its constituent spectral colors (the colors of the rainbow) – thereby making the twilight phenomenon all the more spectacular.^[1]

The exhaust plume may also take on a corkscrew appearance as it is whipped around by upper-level wind currents. It is typically seen within two to three minutes after a launch has occurred. Depending on weather conditions, it could remain in the sky for up to half an hour before dispersing.

At Vandenberg AFB in California, more than 1,800 missiles and space boosters have been launched from the central California coastline in northern Santa Barbara County since December 1958. However, only a small percentage of these launches have created the twilight phenomenon. The same is true with the U.S. Navy's Strategic Systems Programs, which conducts Trident II (D5) missile test flights at sea from Ohio Class SSBN submarines in the Pacific Test Range off the coast of Southern California, or Kokola Point at Barking Sands on the Hawaiian island of Kauai.

Some observers have wrongly assumed the missile or rocket creating the aerial spectacle must have malfunctioned or been destroyed while in flight. That belief stems from the appearance of the launch vehicle's contrail as it becomes twisted into knots by upper altitude air currents or wind shear. To date, no malfunctioning missile or rocket has been known to create the phenomenon. On the rare occasions when a missile or rocket does malfunction, it is destroyed by a Range Safety Officer before reaching the altitudes where twilight phenomenon occur.

The phenomenon's appearance and intensity varies with viewer location and weather conditions—typically, clear skies with no moonlight, since cloud cover would block one's view. The phenomenon can usually be seen throughout the state of California, and as far away as Arizona, Nevada and Utah. On the East Coast, similar sightings were observed and reported during twilight launches of the Space Shuttle from NASA's Kennedy Space Center, and observed after other expendable launch vehicles from the U.S. Space Force's launch complexes at Cape Canaveral Space Force Station in Florida.

External videos
Time-lapse of rocket exhaust above the Sea of Japan in the evening of December 9, 2022.

Numerous nations with a space program — such as the European Space Agency, the Russian Space Agency, the China National Space Agency, Japan's JAXA, India's ISRO and other countries have experienced the same event.