The conversion equations depend on the temperature at which the conversion is wanted (usually about 20 to 25 degrees Celsius). At an ambient air pressure of 1 atmosphere (101.325 kPa), the general equation is:

${\displaystyle \mathrm {ppmv} =\mathrm {mg} /\mathrm {m} ^{3}\cdot {\frac {(0.08205\cdot T)}{M}}}$ 

and for the reverse conversion:

${\displaystyle \mathrm {mg} /\mathrm {m} ^{3}=\mathrm {ppmv} \cdot {\frac {M}{(0.08205\cdot T)}}}$ 

Notes:

• Pollution regulations in the United States typically reference their pollutant limits to an ambient temperature of 20 to 25 °C as noted above. In most other nations, the reference ambient temperature for pollutant limits may be 0 °C or other values.
• 1 percent by volume = 10,000 ppmv (i.e., parts per million by volume).
• atm = absolute atmospheric pressure in atmospheres
• mol = gram mole

Atmospheric pollutant concentrations expressed as mass per unit volume of atmospheric air (e.g., mg/m³, µg/m³, etc.) at sea level will decrease with increasing altitude because the atmospheric pressure decreases with increasing altitude.

The change of atmospheric pressure with altitude can be obtained from this equation:^[2]

${\displaystyle P_{a}=0.9877^{a}}$ 

Given an atmospheric pollutant concentration at an atmospheric pressure of 1 atmosphere (i.e., at sea level altitude), the concentration at other altitudes can be obtained from this equation:

${\displaystyle C_{a}=C\cdot 0.9877^{a}}$ 

As an example, given a concentration of 260 mg/m³ at sea level, calculate the equivalent concentration at an altitude of 1,800 meters:

C_a = 260 × 0.9877 ¹⁸ = 208 mg/m³ at 1,800 meters altitude

A normal cubic meter (Nm³ ) is the metric expression of gas volume at standard conditions and it is usually (but not always) defined as being measured at 0 °C and 1 atmosphere of pressure.

A standard cubic foot (scf) is the USA expression of gas volume at standard conditions and it is often (but not always) defined as being measured at 60 °F and 1 atmosphere of pressure. There are other definitions of standard gas conditions used in the USA besides 60 °F and 1 atmosphere.

That being understood:

1 Nm³ of any gas (measured at 0 °C and 1 atmosphere of absolute pressure) equals 37.326 scf of that gas (measured at 60 °F and 1 atmosphere of absolute pressure).

1 kmol of any ideal gas equals 22.414 Nm³ of that gas at 0 °C and 1 atmosphere of absolute pressure ... and 1 lbmol of any ideal gas equals 379.482 scf of that gas at 60 °F and 1 atmosphere of absolute pressure.

Notes:

• kmol = kilomole or kilogram mole
• lbmol = pound mole

Meteorological data includes windspeeds which may be expressed as statute miles per hour, knots, or meters per second. Here are the conversion factors for those various expressions of windspeed:

1 m/s = 2.237 statute mile/h = 1.944 knots
1 knot = 1.151 statute mile/h = 0.514 m/s
1 statute mile/h = 0.869 knots = 0.447 m/s

Note:

• 1 statute mile = 5,280 feet = 1,609 meters

Many environmental protection agencies have issued regulations that limit the concentration of pollutants in gaseous emissions and define the reference conditions applicable to those concentration limits. For example, such a regulation might limit the concentration of NOx to 55 ppmv in a dry combustion exhaust gas corrected to 3 volume percent O₂. As another example, a regulation might limit the concentration of particulate matter to 0.1 grain per standard cubic foot (i.e., scf) of dry exhaust gas corrected to 12 volume percent CO₂.

Environmental agencies in the USA often denote a standard cubic foot of dry gas as "dscf" or as "scfd". Likewise, a standard cubic meter of dry gas is often denoted as "dscm" or "scmd" (again, by environmental agencies in the USA).

Correcting to a dry basis edit

If a gaseous emission sample is analyzed and found to contain water vapor and a pollutant concentration of say 40 ppmv, then 40 ppmv should be designated as the "wet basis" pollutant concentration. The following equation can be used to correct the measured "wet basis" concentration to a "dry basis" concentration:^[3]

${\displaystyle dry\;basis\;concentration=(wet\;basis\;concentration)/(1-w)}$ 

Thus, a wet basis concentration of 40 ppmv in a gas having 10 volume percent water vapor would have a dry basis concentration = 40 ÷ ( 1 - 0.10 ) = 44.44 ppmv.

Correcting to a reference oxygen content edit

The following equation can be used to correct a measured pollutant concentration in an emitted gas (containing a measured O₂ content) to an equivalent pollutant concentration in an emitted gas containing a specified reference amount of O₂:^[4]

${\displaystyle C_{r}=C_{m}\cdot {\frac {(20.9-r)}{(20.9-m)}}}$ 

Thus, a measured NO_x concentration of 45 ppmv (dry basis) in a gas having 5 volume % O₂ is
45 × ( 20.9 - 3 ) ÷ ( 20.9 - 5 ) = 50.7 ppmv (dry basis) of NO_x when corrected to a gas having a specified reference O₂ content of 3 volume %.

Correcting to a reference carbon dioxide content edit

The following equation can be used to correct a measured pollutant concentration in an emitted gas (containing a measured CO₂ content) to an equivalent pollutant concentration in an emitted gas containing a specified reference amount of CO₂:^[5]

${\displaystyle C_{r}=C_{m}\cdot {\frac {r}{m}}}$ 

Thus, a measured particulates concentration of 0.1 grain per dscf in a gas that has 8 volume % CO₂ is
0.1 × ( 12 ÷ 8 ) = 0.15 grain per dscf when corrected to a gas having a specified reference CO₂ content of 12 volume %.

Notes:

• Although ppmv and grains per dscf have been used in the above examples, concentrations such as ppbv (i.e., parts per billion by volume), volume percent, grams per dscm and many others may also be used.
• 1 percent by volume = 10,000 ppmv (i.e., parts per million by volume).
• Care must be taken with the concentrations expressed as ppbv to differentiate between the British billion which is 10¹² and the USA billion which is 10⁹.

• Standard conditions of temperature and pressure
• Units conversion by factor-label
• Atmospheric dispersion modeling
• Roadway air dispersion modeling
• Bibliography of atmospheric dispersion modeling
• Accidental release source terms
• Choked flow

• More conversions and formulas useful in air dispersion modeling are available in the feature articles at www.air-dispersion.com^{[dead link]}.
• U.S. EPA tutorial course^{[dead link]} has very useful information.