Vinyldiphenylphosphine Knowpia

Vinyldiphenylphosphine
Names
	Preferred IUPAC name Ethenyldi(phenyl)phosphane
	Other names Diphenylvinylphosphine
Identifiers
CAS Number	2155-96-6;
3D model (JSmol)	Interactive image;
ChemSpider	67635;
ECHA InfoCard	100.016.782
EC Number	218-459-2;
PubChem CID	75083;
UNII	HY2FYN4CVS ;
CompTox Dashboard (EPA)	DTXSID80175886 ;
	InChI InChI=1S/C14H13P/c1-2-15(13-9-5-3-6-10-13)14-11-7-4-8-12-14/h2-12H,1H2 Key: AJVBXLXLODZUME-UHFFFAOYSA-N;
	SMILES C=CP(C1=CC=CC=C1)C2=CC=CC=C2;
Properties
Chemical formula	C14H13P
Molar mass	212.232 g·mol−1
Appearance	colorless solid
Melting point	70.5–71.5 °C (158.9–160.7 °F; 343.6–344.6 K)
Boiling point	104 °C (219 °F; 377 K)
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Vinyldiphenylphosphine is the organophosphorus compound with the formula (C₆H₅)₂PCH=CH₂. This colorless, air-sensitive solid is used as a precursor to ligands used in coordination chemistry and homogeneous catalysis.^[1] It is prepared by treating chlorodiphenylphosphine with vinyl Grignard reagents.^[2]

References edit

^ King, R. Bruce (1972). "Poly(tertiary Phosphines) and Their Metal Complexes". Accounts of Chemical Research. 5 (5): 177–185. doi:10.1021/ar50053a003.
^ Rabinowitz, Robert; Pellon, Joseph (1961). "Phosphorus-containing monomers. I. Synthesis of Vinyl Phosphines, Oxides, Sulfides, and Phosphonium Compounds". Journal of Organic Chemistry. 26 (11): 4623–6. doi:10.1021/jo01069a101.