The volume fraction coincides with the volume concentration in ideal solutions where the volumes of the constituents are additive (the volume of the solution is equal to the sum of the volumes of its ingredients).
The sum of all volume fractions of a mixture is equal to 1:
The volume fraction (percentage by volume, vol%) is one way of expressing the composition of a mixture with a dimensionless quantity; mass fraction (percentage by weight, wt%) and mole fraction (percentage by moles, mol%) are others.
Volume percent is the concentration of a certain solute, measured by volume, in a solution. It has as a denominator the volume of the mixture itself, as usual for expressions of concentration, rather than the total of all the individual component's volumes prior to mixing:
The percentage by volume (vol%) is one way of expressing the composition of a mixture with a dimensionless quantity; mass fraction (percentage by weight, wt%) and mole fraction (percentage by moles, mol%) are others.
In the case of a mixture of ethanol and water, which are miscible in all proportions, the designation of solvent and solute is arbitrary. The volume of such a mixture is slightly less than the sum of the volumes of the components. Thus, by the above definition, the term "40% alcohol by volume" refers to a mixture of 40 volume units of ethanol with enough water to make a final volume of 100 units, rather than a mixture of 40 units of ethanol with 60 units of water. The "enough water" is actually slightly more than 60 volume units, since water-ethanol mixture loses volume due to intermolecular attraction.
Volume fraction is related to mass fraction,
where is the constituent density, and is the mixture density.