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Lithium hypochlorite 
Summary
Lithium hypochlorite is a chemical compound with the chemical formula of LiOCl. It is the lithium salt of hypochlorous acid. It consists of lithium cations (Li+) and hypochlorite anions (−OCl). It is a colorless, crystalline compound. It is used as a disinfectant for pools and a reagent for some chemical reactions.
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| ECHA InfoCard | 100.034.130 | ||
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| Properties | |||
| LiOCl | |||
| Molar mass | 58.39 g·mol−1 | ||
| Appearance | Colorless or white crystalline solid | ||
| Odor | chlorine-like odor | ||
| Density | 0.531 g/cm3 (20 °C) | ||
| Melting point | 135 °C (275 °F; 408 K) | ||
| Boiling point | 1,336 °C (2,437 °F; 1,609 K) | ||
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Other anions
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Other cations
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| > 180 °C (356 °F; 453 K) | |||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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Safety edit
Doses of 500 mg/kg cause detrimental clinical signs and significant mortality in rats.[1] The use of chlorine-based disinfectants in domestic water, although widespread, has led to some controversy due to the formation of small quantities of harmful byproducts such as chloroform. Studies showed no uptake of lithium if pools with lithium hypochlorite have been used.[2]
See also edit
References edit
- ^ Hoberman A. M.; Deprospo J. R.; Lochry E. A.; Christian M. S. (1990). "Developmental toxicity study of orally administered lithium hypochlorite in rats". Journal of the American College of Toxicology. 9 (3): 367–379. doi:10.3109/10915819009078746. S2CID 97957731.
- ^ McCarty J. D.; Carter S. P.; Fletcher M. J.; Reape M. J. (1994). "Study of lithium absorption by users of spas treated with lithium ion". Hum Exp Toxicol. 13 (5): 315–9. doi:10.1177/096032719401300506. PMID 8043312. S2CID 27971592.
- Weiner ML, Batt KJ, Putman DL, Curren RD, Yang LL (1990). "Genotoxicity evaluation of lithium hypochlorite". Toxicology. 65 (1–2): 1–22. doi:10.1016/0300-483X(90)90075-R. PMID 2274961.
- Davies NL (1991). "Lithium toxicity in two dogs". J. S. Afr. Vet. Assoc. 62 (3): 140–142. doi:10.4102/jsava.v62i3.1771. PMID 1770485.