MCPB

Summary

MCPB, 2,4-MCPB, 4-(4-chloro-o-tolyloxy)butyric acid (IUPAC), or 4-(4-chloro-2-methylphenoxy)butanoic acid (CAS) is a phenoxybutyric herbicide. In the United States it is registered for use on pea crops before flowering, for post-emergence control of broadleaf annual and perennial weeds including Canadian thistle, buttercup, mustard, purslane, ragweed, common lambsquarters, pigweed, smartweed, sowthistle, and morning glory. It has low to moderate acute toxicity, with kidney and liver effects as the main hazard concerns. It is not volatile, persistent, or likely to bioconcentrate.

MCPB
Skeletal formula of MCPB
Ball-and-stick model of the MCPB molecule
Names
Preferred IUPAC name
4-(4-Chloro-2-methylphenoxy)butanoic acid
Identifiers
  • 94-81-5 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 6938 ☒N
ECHA InfoCard 100.002.151 Edit this at Wikidata
  • 7207
UNII
  • OA1Z4N1842 checkY
  • DTXSID4024193 Edit this at Wikidata
  • InChI=1S/C11H13ClO3/c1-8-7-9(12)4-5-10(8)15-6-2-3-11(13)14/h4-5,7H,2-3,6H2,1H3,(H,13,14) ☒N
    Key: LLWADFLAOKUBDR-UHFFFAOYSA-N ☒N
  • InChI=1/C11H13ClO3/c1-8-7-9(12)4-5-10(8)15-6-2-3-11(13)14/h4-5,7H,2-3,6H2,1H3,(H,13,14)
    Key: LLWADFLAOKUBDR-UHFFFAOYAB
  • CC1=C(C=CC(=C1)Cl)OCCCC(=O)O
Properties
C11H13ClO3
Molar mass 228.67 g/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Infobox references

A variety of methods have been developed for its analysis.[1] In the U.S., the maximum residue permitted on peas is 0.1 parts per million.[2]

References edit

  1. ^ Wells, M. J. M.; Yu, L. Z. (2000). "Solid-phase extraction of acidic herbicides". Journal of Chromatography A. 885 (1–2): 237–250. doi:10.1016/S0021-9673(00)00206-5. PMID 10941675.
  2. ^ "RED FACTS; MCPB". US EPA.

External links edit

  • MCPB in the Pesticide Properties DataBase (PPDB)